FSD100MbP?MbP?dc0dfffffr@м@Harry Kooijman and Ross TaylorCumene_iecr49p719 l$6&ChemSepuAdapted from Luyben et al., Ind. Eng. Chem. Res. (2010) pp. 719-734 Cumene syntheis from Benzene and Propylene. Uxcomponent flows ie9011535AUwNA\t== ie90115354Property pack for flowsheet presented in said paper.ư>MbP?MbP?MbP?K2.C:\Program Files\ChemSepL6v90\pcd\chemsep1.pcdsPropane CH3CH2CH3C3H874-98-6CCCGw@p4PA??l@^U@^U@&?j F@ *?`t? =@`@^U@4w@eG }A3? :?)\U@w@j d@H@-#?>@U@d[@pc@@x@rF?^U@v@=@, (@*?@sb@p@}"?@3Z vKw.`*^@`f@hj<4@3@ HP?_n@^U@`fv@e@ui>?\}@ 8^U@@@f`+? R0@M@%T,^U@u@ X9 ?LUA] 8 l@@@f)`>1@ ~/?b )\U@ w@<@`TE@@e?E .>I@@@d 8 8 8 8 8 8 8= 5@1@)\* 8 8k@t@ v@k~ ? 8 8^U@`fv@ Tt$6@fffff7nfQ|?-bm>@@T@T@෯?@ ? 8Mo?8??6?uq?P@ *?Ծu@Pm@@?oa?n PropyleneCH2CHCH3C3H6115-07-1C=CC v@0QA?`?`f.l@U@U@U+S?3 E@KO?{?@=9@ 9r?(AJsA|ލAKA`fFA 8޳4@@r 8 8 8IR@`fV@@f?s?Gv@? 8U@v@iV@@&6>@U@v@e?zA?Gڿr??U@v@jU`9dG@ges?,@U@dz@r@k@?>`fU@@u@ @̢@`'@]$??@t^@p@? U`@3{|@f@p@h৶T0@n)@@U@`ft@eɨ>!Y?Gep@ [ 8U@@@fԦ6@l6X?`JdU@Gu@`?@33?Gy@`f@ 8`f.l@@@f툿%@~@^<reU@v@`۳@r4l@Ȕ> 8i@@ 8 8 8 8 8 8 84@2@@b2 8 8`bk@yt@ `7B? 8 8U@`ft@ n\@3333}r?T㥛Ā0C 5@@(@(@`?@3@? 8_>y?Hh??੫?b? N@KO?(*t@n@S???mBenzene-CHCHCHCHCHCH-C6H671-43-2c1ccccc1`f@FRAMb?&?v@@jq@@jq@`8@KS@? ?`=C@Ǩ?A“A(AoAbbA 8r]@5*@6 8 8 8q@q@?@?`f@`? 8q@`f@i@V@`8C $@">@q@G@e@FA?п??q@`f@j@ '_)h@-2`*o?D@@3kq@d@6@@3$f6@ f`6f>@jq@@@ B@)@`)+`3j>i@p@h?)k2L@Qq@@h)8@ [@aվ@@jq@@e`>? @ A 8q@@@f-]?@ ?f`?;~o>q@y@H>:?zDc@@ 8@o@@@f@5^jTwx`IC>q@`f@@@@`I C?.Z@>I@@@d 8 8 8 8 8 8 8@35@B@D 8 8 u@`f@ `&5> 8 8@jq@@ |?5.[@@W;?Cl,f"-ܾ@@ @@33@@33@C?1L@ ? 8'4Y?h?j?@j>?Wʢ?pV@?&@ t@` A??Cumene(C6H5)CH(CH3)2C9H1298-82-8c1(C(C)C)ccccc1@{HA ?`9?Qz@z$f@z$f@Q>?j ^@ ? /?W=@`]9@Bx?48ANA_pA@AL[A 8@q#$@y 8 8 8@ Q@z$f@?9]?@ḃ@? 8@3#c@̸@iq@@/@^ZC0>@z$f@`f@e~A? 8 8 8z$f@@jv@%~?$@%f@d`?@ r \+@`9s w">z$f@@@`@ I*@1 =_u>i@p@3?`u@Ru@r@@h 0@3W@`[?`>@i@y@eJn>`#?Gq@`6 8z$f@@@f`?G~@@,!?z$f@@@x>@c? \|@ 8w@@@f s@`G@ rK?K׾z$f@@<@q@ 7?`s[`>I@@@d 8 8 8 8 8 8 8|4@Y@`S 8 8@3w@̐@ ]@0 ^? 8 8i@y@ L@`-@`-@ u? @`? 8AЁ? V?k1??@?c@ ?YW@st@t.)؇=t?`?`?P-diisopropylbenzene(CH3)2CH(C6H4)CH(CH3)2C12H18100-18-5c1(C(C)C)ccc(C(C)C)cc1 @`BA ?Mb?Q8~@Gp@Gp@U?Hd@@Y?#?>@"۹?ATAA 8`8 @2h Y@Gp@@u?@.?@? 8Gp@ ф@i`:`@.>@Gp@@e@&ݖAd@ } @ 6<Gp@ ф@j@@`t@qj"@@r`??I@Gp@d:vW@ &@7s?+;Gp@`f:~@@zx*@?`Yr@p@?`f `b20Au@@@h~!@ֿ>@Gp@`f:~@e [>`z?qx@@ f@ 8`f:~@@@f-AӍ-?@?!Benzene/Isopropylbenzene p322 1/7imported from VANLAAR.IPDѿ Benzene/Isopropylbenzene p322 1/imported from MARGULES.IPD6;Nё? Benzene/Isopropylbenzene p322 1/imported from MARGULES.IPD_X:2b!Benzene/Isopropylbenzene p322 1/7imported from WILSON.IPDyۤ3Ȅ@!Benzene/Isopropylbenzene p322 1/7imported from WILSON.IPDM٤\%@!Benzene/Isopropylbenzene p322 1/7imported from NRTL.IPD0."y!Benzene/Isopropylbenzene p322 1/7imported from NRTL.IPD<CH2C=CACHCH3ͪ?A`"? rh.@CH2N O?HzG?Zd;O ,@CH2=CHI&†?8A`?%C ;@CH F%u?v/?K7 *@ACHqh??K7 *@ACo_?Q?Q(@zGU@q= ףN@GzAGzgC@= ףp=& rh @CH2ACHCH3ͪ?A`"? rh.@CH2N O?HzG?Zd;O ,@ACHqh??K7 *@CH F%u?v/?K7 *@ACo_?Q?Q(@33333\c@CH2ArCHCH3?? rh.@CH??K7 *@ArCH??K7 *@ArC??Q(@|гY??f@b@V瞯< ie9011535New Reaction PackagebKrx-D@ ie9011535-C:\Program Files (x86)\COCO\data\ChemSep1.pcdPropane74-98-6PropaneC3H8j F@ Propylene115-07-1 PropyleneC3H63 E@Benzene71-43-2BenzeneC6H6KS@Cumene98-82-8CumeneC9H12j ^@p-diisopropylbenzene100-18-5p-diisopropylbenzeneC12H18Hd@ Cumene ProdVapor? DISP ProdVapor? ie901153574-98-6Propanej F@l@C3H8 ie9011535Propane115-07-1 Propylene3 E@`f.l@C3H6 ie9011535 Propylene71-43-2BenzeneKS@v@C6H6 ie9011535Benzene98-82-8Cumenej ^@Qz@C9H12 ie9011535Cumene100-18-5p-diisopropylbenzeneHd@8~@C12H18 ie9011535P-diisopropylbenzene ????????????thermalConductivity.Dmoles?? / molexcessEnthalpy.Dpressure??gibbsFreeEnergy.Dpressure??enthalpyF.DmolFraction??viscosity.Dtemperature???? thermalConductivity.Dtemperature??thermalConductivity.Dpressure??enthalpyF.Dpressure??activityCoefficientheatCapacity.DmolFraction??entropyF.Dmoles??enthalpy.Dmoles??density.Dpressure?@?@heatOfVaporization??molecularWeight#logFugacityCoefficient.DmolFractionentropy.Dtemperature??viscosity.Dmoles???? / mol volume.Dmoles@@@@ enthalpyF??enthalpy??vaporPressure.Dtemperature??fugacity.Dtemperature??activity.DmolFractionvolume.Dpressure@@@@excessEnthalpy.Dtemperature??surfaceTension.DmolFraction?? activityCoefficient.DtemperaturefugacityCoefficient.Dmoles / molgibbsFreeEnergy??gibbsFreeEnergy.DmolFraction??activityCoefficient.Dmoles / molactivity.Dmoles / molenthalpy.DmolFraction??logFugacityCoefficiententhalpy.Dpressure??activitymolecularWeight.Dtemperature fugacityCoefficient.DmolFractionfugacity.Dpressurevolume.DmolFraction@@@@density?@?@activity.DtemperatureenthalpyF.Dtemperature??surfaceTension.Dtemperature??thermalConductivity??entropyF.DmolFraction??surfaceTension??density.DmolFraction?@?@heatCapacity.Dtemperature??#logFugacityCoefficient.DtemperatureexcessEnthalpy??viscosity.DmolFraction????fugacityCoefficient.DpressuresurfaceTension.Dmoles?? / molentropy.Dpressure??enthalpy.Dtemperature??gibbsFreeEnergy.Dmoles?? thermalConductivity.DmolFraction??density.Dmoles?@?@ / mollogFugacityCoefficient.Dmoles / molidealGasEnthalpy.Dtemperature??surfaceTension.Dpressure??enthalpyF.Dmoles??heatOfVaporization.Dtemperature??entropyF.Dtemperature??entropy.DmolFraction??volume@@@@entropyF??entropy??molecularWeight.DpressureheatCapacity.Dpressure??gibbsFreeEnergy.Dtemperature??fugacityCoefficientviscosity.Dpressure?? logFugacityCoefficient.DpressureidealGasEnthalpy?? heatCapacity?? fugacityCoefficient.DtemperatureentropyF.Dpressure??entropy.Dmoles??activityCoefficient.Dpressure viscosity???? activityCoefficient.DmolFractionexcessEnthalpy.Dmoles??volume.Dtemperature@@@@fugacity.Dmoles?? / moldensity.Dtemperature?@?@heatCapacity.Dmoles??molecularWeight.DmolFractionactivity.DpressuremolecularWeight.Dmoles / molexcessEnthalpy.DmolFraction??@ &{779B2C7A-F54B-4A1D-B345-7FA14B889642}Outlet temperature?? Heat duty?? Pressure drop??TotalMassBalancePropertiesFraction? TotalFlowMass??&{E813F646-A25E-4B14-8873-4853D1AA3252}Pressure increase??Pressure?? Energy demand??Adiabatic efficiency?&{7A1D05E4-54D2-483F-8BC8-3D4D2DA1897E} Temperature?? Heat exchange?? Heat transfer??Pressure drop stream 1??Pressure drop stream 2?? Tolerance?&{74475174-0CAC-48E0-93D5-90276104D854}Pressure difference??Pressure??&{603DF4B9-4F88-475D-A458-85F56125DA70} Pressure drop?? Temperature?? Heat duty??)Conversion Propylene reaction Cumene Prod?'Conversion Propylene reaction DISP Prod?&{BD25A684-3814-4212-84CD-76D752E106EE} Pressure drop??Pressure?? Heat duty?? Temperature??Vapor fraction?&{71F5AC07-65A1-4357-8F1B-A8CD58148763}RelativePerturbationTemperature?RelativePerturbationPressure?PerturbationComposition?Temperature profile??Pressure profile??Vapour Flow profile??Liquid Flow profile??Duties profile??Vapour Density profile@?@?Vapour Viscosity profile????Vapour Heat capacity profile??#Vapour Thermal conductivity profile??Liquid Density profile@?@?Liquid Viscosity profile????Liquid Heat capacity profile??Liquid Thermal cond. profile??Surface tension profile??&{5E216BDD-C82F-45FE-830C-61FDDD2D9BC7} Pressure drop??&{D1F7CEE3-4C3A-4D05-890A-6B3D97AD1F67}&{81212F14-4C54-43C0-BFA8-B9C163C9148C} Outlet flow??Net flow??&{429DC999-9073-4549-8647-BA72D6BE7931}Pressure increase??Pressure?? Energy demand??Isentropic efficiency?dheatOfVaporizationheatOfVaporization.DtemperatureidealGasEnthalpyidealGasEnthalpy.Dtemperature vaporPressurevaporPressure.Dtemperatureactivityactivity.Dmolesactivity.DmolFractionactivity.Dpressureactivity.DtemperatureactivityCoefficientactivityCoefficient.Dmoles activityCoefficient.DmolFractionactivityCoefficient.Dpressure activityCoefficient.Dtemperaturedensitydensity.Dmolesdensity.DmolFractiondensity.Dpressuredensity.Dtemperatureenthalpyenthalpy.Dmolesenthalpy.DmolFractionenthalpy.Dpressureenthalpy.Dtemperature enthalpyFenthalpyF.DmolesenthalpyF.DmolFractionenthalpyF.DpressureenthalpyF.Dtemperatureentropyentropy.Dmolesentropy.DmolFractionentropy.Dpressureentropy.DtemperatureentropyFentropyF.DmolesentropyF.DmolFractionentropyF.DpressureentropyF.DtemperatureexcessEnthalpyexcessEnthalpy.DmolesexcessEnthalpy.DmolFractionexcessEnthalpy.DpressureexcessEnthalpy.Dtemperaturefugacityfugacity.Dmolesfugacity.DmolFractionfugacity.Dpressurefugacity.DtemperaturefugacityCoefficientfugacityCoefficient.Dmoles fugacityCoefficient.DmolFractionfugacityCoefficient.Dpressure fugacityCoefficient.DtemperaturegibbsFreeEnergygibbsFreeEnergy.DmolesgibbsFreeEnergy.DmolFractiongibbsFreeEnergy.DpressuregibbsFreeEnergy.Dtemperature heatCapacityheatCapacity.DmolesheatCapacity.DmolFractionheatCapacity.DpressureheatCapacity.DtemperaturelogFugacityCoefficientlogFugacityCoefficient.Dmoles#logFugacityCoefficient.DmolFraction logFugacityCoefficient.Dpressure#logFugacityCoefficient.DtemperaturemolecularWeightmolecularWeight.DmolesmolecularWeight.DmolFractionmolecularWeight.DpressuremolecularWeight.DtemperaturethermalConductivitythermalConductivity.Dmoles thermalConductivity.DmolFractionthermalConductivity.Dpressure thermalConductivity.Dtemperature viscosityviscosity.Dmolesviscosity.DmolFractionviscosity.Dpressureviscosity.Dtemperaturevolume volume.Dmolesvolume.DmolFractionvolume.Dpressurevolume.DtemperaturesurfaceTensionsurfaceTension.DmolessurfaceTension.DmolFractionsurfaceTension.DpressuresurfaceTension.DtemperaturebubblePointTemperaturebubblePointPressuredewPointTemperaturedewPointPressureVapor Vapor phase ie9011535VaporLiquid Liquid phase ie9011535Liquid VaporLiquiddefaultdefault material template ie9011535C3=+++ ntConstadefaultCAfffffr@KI<@2x?`zsѐ?ߣ2?ZHf?t\T?azsѐ?ߣ2?ZHf?t\T??`zsѐ?ߣ2?ZHf?t\T?`zsѐ?ߣ2?ZHf?t\T?fffffr@CAKI<@2x?Benzene D@defaultCAfffffr@rqK@8[@???????fffffr@CArqK@8[@4+ $ +$$ + defaultCA@t@L@r:@b,?koM>?KQk-H`?;FQ?VVX?6ya?G6wMo?bmxHx?&"{/=Jag@=?b,?ioM>?JQk-H`?:FQ?TVX?6ya?G6wMo?`mxHx?$"{/=Jag@=251 ; 6 1 ; 1 ; defaultCA>ns@'}'U@U@V|ߟ?4h?C}r?_l7?hh?F6dנ?eЛd?ّXs?[L0%= !x0:=?V|ߟ?4h?C}r?_l7?hh?F6dנ?eЛd?ّXs?[L0%= !x0:=27? 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D D defaultCAgffff2~@'}'U@U@V|ߟ?4h?C}r?_l7?hh?F6dנ?eЛd?ّXs?[L0%= !x0:=?V|ߟ?4h?B}r?_l7?hh?F6dנ?eЛd?ؑXs?[L0%= !x0:=28JR K JR JJ R defaultCA;r8@'}'U@U@V|ߟ?4h?C}r?_l7?hh?F6dנ?eЛd?ّXs?[L0%= !x0:=?V|ߟ?4h?C}r?_l7?hh?F6dנ?eЛd?ّXs?[L0%= !x0:=29V ^ Z V ^ V ^ defaultCA333339@'}'U@U@V|ߟ?4h?C}r?_l7?hh?F6dנ?eЛd?ّXs?[L0%= !x0:=?V|ߟ?2h?C}r?_l7?hh?F6dנ?eЛd?ؑXs?[L0%= !x0:=210l JgJr l r rrJJr defaultCA33333@aBM@@ۜ"R?S0h?Mχ%=%@%=%@% default\AsF}v@gaBM@:@=$R?h?χ?Mۜz?ͪWH2?J/0?5ޅA9?Ƅ?@Qx`?,z[L?QI ?_a?̪ ċ?z*)?[&s?tɘ?2148!:%8$8!:%8!8%:% defaultCAgffffv@gaBM@:@=$R?h?χ@";}?1N?"io??_ފGa?9o6K?2?$aS~?=EoeJP=Uم;?κ h?hyaT?zާU?=v@| ?@"ab?Ei? <|(?qW#=EoeJP=218ZG`7]?Z7`GZG]G]>]7`7]> $default\AwȐ{@]2:@ @ԗM=2i 5=& =:t<Mb@?Γ5?~H?C?td?n_˔? ˰=ʝ=;r=wXfZ=盰d?YR@,Z?ΐ??MJbl1y???ԗM=2i 5=& =:t<Mb@?Γ5?~H?C?td?n_˔?219c7f7d7c7f7c7f7 defaultj@D%~{z@]2:@ @ԗM=2i 5=& =:t<Mb@?Γ5?~H?C?td?n_˔?\v?v*u=p>_=f|92=$i=qZ?P?o!ob?[| Y?Ly?I# ?iQDR?e =0_<č_D6>E?c?U#Lj>}.*`k>8?2??4=>F6>I?f?d1         defaultCAfffffr@6Ŵ;@IqS@?????227D888DDD88 defaultCA )qu@gaBM@:@=$R?h?χ?A ?:ψ?ۻe?228 defaultCA /t@T9s~=@(N@>@";}?1N?"io??_ފGa?9o6K?2?$aS~?=EoeJP=?";}?1N?"io??_ފGa?9o6K?2?$aS~?=EoeJP=2 Mixer_26Mixer - mix 2 or more inlet streams to a single outletk!^/E a-COUSCOUS0002Number of inletsNumber of inlet ports Pressure dropPressure drop along the mixer?? _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last runD+++ specifications +++ Number of inlets: 2 Pressure drop: 0 Pa +1 $not all material ports are connectedInlet 2Inlet 1Outlet0@@@@@@@ @ VaporizerMHeaterCooler - heat or cool stream specifying heat duty or outlet temperaturez,wKJEKBCOUSCOUS0002TypeType of heat duty specification Temperature Heat duty Heat duty Temperature Energy inletOutlet temperature!Temperature of the product stream?gffff2~@r@ _B Heat duty Heat duty@?@c>eIA@x@xD Pressure dropPressure drop along the unit?? _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Heat duty: 3393397.08861154 W Pressure drop: 0 Pa +++ optional parameters +++ Outlet temperature: 483.15 K ;? $not all material ports are connectedInletOutlet B4mwp0mw:,>8,>СBB4mwp0mw:,>8,>СBB4mwp0mw:,>8,>СBB4mwp0mw:,>8,>СB@@ ɿ@????@@@@@ɿ@@@HX1MHeaterCooler - heat or cool stream specifying heat duty or outlet temperaturez,wKJEKBCOUSCOUS0002TypeType of heat duty specification Temperature Heat duty Heat duty Temperature Energy inletOutlet temperature!Temperature of the product stream?333339@r@ _B Heat duty Heat duty@?@9Ȥ*A@x@xD Pressure dropPressure drop along the unit?? _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Heat duty: 873539.797325186 W Pressure drop: 0 Pa +++ optional parameters +++ Outlet temperature: 647.15 K RV $not all material ports are connectedInletOutlet d qw:lwlwfCd qw:lwlwfCd qw:lwlwfCd qw:lwlwfC@@ ɿ@????@@@@@ɿ@@@ReactorGFixedConversionReactor - perform reactions using a specified conversion=`O]GXa%pCOUSCOUS0002 Pressure dropPressure drop over the reactor?? _BHeat duty typeType of heat duty specification Isothermal Isothermal Isothermal Heat duty Energy inlet TemperatureReactor effluent temperature?33333@r@ _B Heat dutyReactor heat duty@?@un? _ _B Enthalpy TypeEnthalpy calculation type Use EnthalpyF Use EnthalpyF Use EnthalpyF"Use Enthalpy (no heat of reaction)!Use Enthalpy and heat of reactionThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Cumene Prod PropylenezG? DISP Prod Propylene;v?Last run+++ specifications +++ Using enthalpyF in enthalpy calculations Heat duty type: Isothermal Temperature: 692.15 K Pressure drop: 0 Pa +++ optional parameters +++ Heat duty: -2059893.81295512 W ^l $not all material ports are connected ie9011535InletOutlet  @@ @@ @@ @@ @@ ??@@@@@Valve_91Valve - generates power from pressure difference.tQGt HՐ'aTLCOUSCOUS0002Pressure spec. Pressure drop specification typePressurePressure differencePressure differencePressurePressure differencePressure drop along the valve??AA _BPressureValve outlet pressure?\Aj@ _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last runq+++ specifications +++ Pressure: 175000 Pa +++ optional parameters +++ Pressure difference: 2325000 Pa :$=& $not all material ports are connected InletOutlet0@@@@@gUUUUU?@HeaterCooler_10MHeaterCooler - heat or cool stream specifying heat duty or outlet temperaturez,wKJEKB COUSCOUS0002TypeType of heat duty specification Temperature Heat duty Heat duty Temperature Energy inletOutlet temperature!Temperature of the product stream?gffffv@r@ _B Heat duty Heat duty@?@w׬P@x@xD Pressure dropPressure drop along the unit?? _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Heat duty: -4371306.40913182 W Pressure drop: 0 Pa +++ optional parameters +++ Outlet temperature: 363.15 K 6:! $not all material ports are connectedInlet Outlet d qw:lwlwEd qw:lwlwEd qw:lwlwEd qw:lwlwE@@ @@?@?@@?@?ɿɿ@@@C1ChemSep Unit OperationqeWCXcCSUOk[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_A_F~1.sep Title=ChemSep CO Unit Operation "C1" in COFE Flowsheet User=Harry Date=2012-02-03 Time=08:21:32 [Cape-Open] unitname=C1 CO_ID=CS_A_F94_1CCE244_725F3F40 5 components Propane 74-98-6 44.0970001221 Mw Propylene 115-07-1 42.07970047 Mw Benzene 71-43-2 78.1139984131 Mw Cumene 98-82-8 120.194000244 Mw p-diisopropylbenzene 100-18-5 162.27130127 Mw 1 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=TRUE WilsonEstimate=TRUE Status= 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=C Flow=kmol/h Mass flow=kg/s Pressure=bar Heat=MW Enthalpy=kJ/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=deg Velocity=m/s Surface tension=dyn/cm Density=kg/m3 Molar density=kmol/m3 Viscosity=Pa.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=1e-8 m2/s Interaction parameter=J/mol Time=s [Components] 5 67 3 Library Offset, Index DT=2012-01-31,09:17:24 CHK=60240 CAS=74-98-6 CID=Propane Name=Propane Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 61 202 Library Offset, Index DT=2012-01-31,09:17:24 CHK=29371 CAS=115-07-1 CID=Propylene Name=Propylene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 125 501 Library Offset, Index DT=2012-01-31,09:17:24 CHK=23428 CAS=71-43-2 CID=Benzene Name=Benzene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 163 510 Library Offset, Index DT=2012-01-31,09:17:24 CHK=5750 CAS=98-82-8 CID=Cumene Name=Cumene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 1 544 Library Offset, Index DT=2011-12-15,01:03:44 CHK=53139 CAS=100-18-5 CID=p-diisopropylbenzene Name=p-diisopropylbenzene Lib=h:\downloads\lyubenaichem2011\diisopropylbenzene.pcd [Operation] 2 Operation Column 1 Operation kind Simple Distillation 1 Condenser Total (Liquid product) 1 Reboiler Partial (Liquid product) 15 Stages 1 Feed stages 0 Sidestream stages F=8 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 2 K model EOS * * Activity coefficient * * Wilson model * * UNIQUAC model * 3 Equation of State Cubic 5 Cubic EOS Peng-Robinson 76 * Virial EOS * 1 Vapour pressure Antoine 0 Henry's law * Henry's default * [Enthalpy] 6 Enthalpy Peng-Robinson 76 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 0 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Property Data] [Peng-Robinson 76 Data] i j kij Component Component 1 2 0.0063 Propane/Propylene 1 3 0.0233 Propane/Benzene [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Heaters/Coolers] 0 Number 0 Column duty Qcolumn 2 First stage 14 Last stage 0 Qcolumn lost to surroundings [Efficiencies] 1 Default efficiency 0 Number [Pressures] 1 Column pressure Constant pressure 175000 Condenser pressure 175000 Top pressure * Pressure Drop * Bottom pressure [Feeds] 1 Number 1 Feed state T & p 8 Stage Feed1{split} 363.15 Temperature 186986.074012 Pressure 0 Vapour fraction 5 componentflows 0.00124535767822 Component 1 flow 0.000114308324431 Component 2 flow 0.0281038525374 Component 3 flow 0.0260651673061 Component 4 flow 0.00071813496227 Component 5 flow [Condenser] 1 Type Reflux ratio 0.44 Value Qcondenser 1 Type Reflux ratio 1 Initialization guess [Reboiler] 7 Type Mole fraction of a component 0.0005 Value Qreboiler 3 1st comp. 4 Type Bottom product flow rate 0.0277778 Initialization guess [Monitored Variables] * [Solve options] 3 Initialization Old Results 1 Method Newton's method 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 30 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 y1 x2 y2 StringGrid=StringGrid3 1 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 2 ComboBox=ComboBox23 3 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram Benzene - Cumene Xlabel X Benzene/(Benzene+Cumene) Ylabel Y Benzene/(Benzene+Cumene) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 2 ComboBox=ComboBox76 3 ComboBox=ComboBox77 0 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Title ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 8 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 6 7 Identifier L# File Loc. CAS SMILES Name Propane 3 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 67 74-98-6 CCC Propane Propylene 202 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 61 115-07-1 C=CC Propylene Benzene 501 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 125 71-43-2 c1ccccc1 Benzene Cumene 510 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 163 98-82-8 c1(C(C)C)ccccc1 Cumene p-diisopropylbenzene 544 h:\downloads\lyubenaichem2011\diisopropylbenzene.pcd 1 100-18-5 c1(C(C)C)ccc(C(C)C)cc1 p-diisopropylbenzene 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 1 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 331.8666109 1.750000000E+05 2.966989823E-02 1.305475522E-02 -1.461799455E+06 2 372.0984248 1.750000000E+05 4.272465344E-02 1.429789198E-02 0.000000000E+00 3 376.2358368 1.750000000E+05 4.396779021E-02 1.326041811E-02 0.000000000E+00 4 382.0406508 1.750000000E+05 4.293031634E-02 1.215498197E-02 0.000000000E+00 5 388.2347374 1.750000000E+05 4.182488019E-02 1.145101649E-02 0.000000000E+00 6 392.6262821 1.750000000E+05 4.112091471E-02 1.112794160E-02 0.000000000E+00 7 394.9947004 1.750000000E+05 4.079783982E-02 1.095200072E-02 0.000000000E+00 8 396.3837422 1.750000000E+05 4.062189894E-02 7.351510476E-02 0.000000000E+00 9 410.8680447 1.750000000E+05 4.693818218E-02 7.269213578E-02 0.000000000E+00 10 427.9302850 1.750000000E+05 4.611521320E-02 7.460047670E-02 0.000000000E+00 11 439.9883370 1.750000000E+05 4.802355412E-02 7.774282262E-02 0.000000000E+00 12 445.4893076 1.750000000E+05 5.116590004E-02 7.965223484E-02 0.000000000E+00 13 447.4923730 1.750000000E+05 5.307531226E-02 8.040831446E-02 0.000000000E+00 14 448.2018617 1.750000000E+05 5.383139187E-02 8.041383613E-02 0.000000000E+00 15 449.1404941 1.750000000E+05 5.383691354E-02 2.657692258E-02 1.930958445E+06 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.2768490E+08 -0.2768490E+08 -0.7653901E+05 -0.7653901E+05 2 0.6529521E+07 -0.2302829E+08 0.1741288E+05 -0.6117620E+05 3 0.7076434E+07 -0.2269267E+08 0.1904366E+05 -0.5669717E+05 4 0.7907627E+07 -0.2210501E+08 0.2210831E+05 -0.5106696E+05 5 0.8887178E+07 -0.2126910E+08 0.2557363E+05 -0.4590785E+05 6 0.9650524E+07 -0.2056243E+08 0.2818385E+05 -0.4253313E+05 7 0.1008812E+08 -0.2015036E+08 0.2964626E+05 -0.4074437E+05 8 0.1033197E+08 -0.1997250E+08 0.3042753E+05 -0.3931013E+05 9 0.1358371E+08 -0.1692778E+08 0.3941209E+05 -0.2936784E+05 10 0.1898200E+08 -0.1262962E+08 0.5414056E+05 -0.1786922E+05 11 0.2423184E+08 -0.9232920E+07 0.6620322E+05 -0.1004823E+05 12 0.2712904E+08 -0.7599851E+07 0.7157678E+05 -0.6667363E+04 13 0.2827172E+08 -0.6993397E+07 0.7319911E+05 -0.5522537E+04 14 0.2867375E+08 -0.6782336E+07 0.7361313E+05 -0.5094525E+04 15 0.2898535E+08 -0.6581529E+07 0.7417826E+05 -0.3718151E+04 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.5385910E+02 0.3523053E+01 0.8931278E-05 0.8315920E+05 0.1946858E-01 2 0.7685890E+02 0.4544808E+01 0.9443086E-05 0.1039526E+06 0.1730805E-01 3 0.7800369E+02 0.4561324E+01 0.9501666E-05 0.1068463E+06 0.1749881E-01 4 0.7920717E+02 0.4558479E+01 0.9581362E-05 0.1112674E+06 0.1796642E-01 5 0.8075016E+02 0.4571363E+01 0.9651496E-05 0.1166410E+06 0.1846602E-01 6 0.8203512E+02 0.4591779E+01 0.9690644E-05 0.1209268E+06 0.1881819E-01 7 0.8279559E+02 0.4606648E+01 0.9708075E-05 0.1234076E+06 0.1900717E-01 8 0.8315336E+02 0.4609998E+01 0.9722400E-05 0.1246643E+06 0.1912202E-01 9 0.9015147E+02 0.4833339E+01 0.9745721E-05 0.1436899E+06 0.1987833E-01 10 0.1008969E+03 0.5218978E+01 0.9616869E-05 0.1752029E+06 0.2109400E-01 11 0.1112894E+03 0.5632446E+01 0.9411664E-05 0.2052164E+06 0.2190857E-01 12 0.1169313E+03 0.5866161E+01 0.9287794E-05 0.2214382E+06 0.2225909E-01 13 0.1191337E+03 0.5958700E+01 0.9238361E-05 0.2277671E+06 0.2238285E-01 14 0.1198883E+03 0.5989940E+01 0.9221873E-05 0.2299510E+06 0.2242714E-01 15 0.1201944E+03 0.5992472E+01 0.9223907E-05 0.2310952E+06 0.2250070E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.7685890E+02 0.8218530E+03 0.3687287E-03 0.1448097E+06 0.1303902E+00 0.2294255E-01 2 0.8037929E+02 0.7920429E+03 0.2668331E-03 0.1590946E+06 0.1198329E+00 0.1877093E-01 3 0.8446138E+02 0.7889782E+03 0.2644460E-03 0.1691046E+06 0.1175107E+00 0.1839464E-01 4 0.9024860E+02 0.7841851E+03 0.2618499E-03 0.1835765E+06 0.1142841E+00 0.1789184E-01 5 0.9544685E+02 0.7785995E+03 0.2586145E-03 0.1972220E+06 0.1112699E+00 0.1736627E-01 6 0.9862429E+02 0.7744754E+03 0.2561144E-03 0.2059646E+06 0.1093569E+00 0.1699892E-01 7 0.1002056E+03 0.7722506E+03 0.2542350E-03 0.2104500E+06 0.1083941E+00 0.1680723E-01 8 0.1014157E+03 0.7716022E+03 0.2438437E-03 0.2138164E+06 0.1078938E+00 0.1679151E-01 9 0.1083600E+03 0.7576211E+03 0.2341860E-03 0.2359800E+06 0.1031670E+00 0.1561004E-01 10 0.1148592E+03 0.7407093E+03 0.2212278E-03 0.2598128E+06 0.9855424E-01 0.1427182E-01 11 0.1184281E+03 0.7286475E+03 0.2099215E-03 0.2751865E+06 0.9594006E-01 0.1334952E-01 12 0.1198598E+03 0.7231120E+03 0.2041329E-03 0.2819757E+06 0.9490816E-01 0.1293579E-01 13 0.1203581E+03 0.7210946E+03 0.2018816E-03 0.2844301E+06 0.9455661E-01 0.1278719E-01 14 0.1205631E+03 0.7204486E+03 0.2003381E-03 0.2853752E+06 0.9443968E-01 0.1274967E-01 15 0.1213097E+03 0.7206490E+03 0.1875606E-03 0.2878110E+06 0.9435637E-01 0.1292986E-01 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.655747450E+00 0.419737765E-01 0.288413510E-01 0.293477078E-01 0.300982571E-01 2 0.543080322E-01 0.385266992E-02 0.265086717E-02 0.269522071E-02 0.276300623E-02 3 0.289739933E+00 0.946769816E+00 0.945544059E+00 0.915946334E+00 0.877795187E+00 4 0.204585000E-03 0.740373779E-02 0.229637224E-01 0.520107369E-01 0.893435385E-01 5 0.728742643E-16 0.109650341E-12 0.639079425E-11 0.303889743E-09 0.110168589E-07 Component Mole fractions on stages: 6 to 10 1 0.305949655E-01 0.308263468E-01 0.309531965E-01 0.171392948E-02 0.864494039E-04 2 0.280788429E-02 0.282878486E-02 0.284028911E-02 0.152008303E-03 0.727183378E-05 3 0.846277852E+00 0.827755195E+00 0.819133915E+00 0.710803220E+00 0.458857567E+00 4 0.120318996E+00 0.138582866E+00 0.146934051E+00 0.287084253E+00 0.540602321E+00 5 0.301492540E-06 0.680774713E-05 0.138548518E-03 0.246589428E-03 0.446390353E-03 Component Mole fractions on stages: 11 to 15 1 0.383470528E-05 0.154463065E-06 0.595500067E-08 0.225901751E-09 0.843531673E-11 2 0.302302606E-06 0.113668545E-07 0.408645768E-09 0.144521451E-10 0.503455866E-12 3 0.212247127E+00 0.782872792E-01 0.259951501E-01 0.816564531E-02 0.236734167E-02 4 0.787104509E+00 0.920960734E+00 0.973206136E+00 0.990933458E+00 0.995254116E+00 5 0.644227532E-03 0.751821311E-03 0.798707299E-03 0.900896896E-03 0.237854212E-02 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.419737765E-01 0.158994017E-02 0.109715252E-02 0.111051725E-02 0.111215339E-02 2 0.385266992E-02 0.156977472E-03 0.105453191E-03 0.103174154E-03 0.100816035E-03 3 0.946769816E+00 0.943000463E+00 0.846979463E+00 0.709430462E+00 0.585900416E+00 4 0.740373779E-02 0.552526193E-01 0.151817930E+00 0.289355809E+00 0.412885532E+00 5 0.109650341E-12 0.194249464E-10 0.983591114E-09 0.379083696E-07 0.108266771E-05 Component Mole fractions on stages: 6 to 10 1 0.110448834E-02 0.109751102E-02 0.109431571E-02 0.548426959E-04 0.246856575E-05 2 0.988490997E-04 0.976636860E-04 0.970547951E-04 0.461318355E-05 0.194605269E-06 3 0.510432206E+00 0.473357441E+00 0.454016894E+00 0.291277767E+00 0.136810786E+00 4 0.488339498E+00 0.524933496E+00 0.534865756E+00 0.698500462E+00 0.853145421E+00 5 0.249589173E-04 0.513888197E-03 0.992597949E-02 0.101623145E-01 0.100411296E-01 Component Mole fractions on stages: 11 to 15 1 0.101658869E-06 0.396811419E-08 0.151305860E-09 0.571760917E-11 0.212344746E-12 2 0.748102059E-08 0.272300153E-09 0.967926124E-11 0.340967521E-12 0.118146266E-13 3 0.516951588E-01 0.174883878E-01 0.563196128E-02 0.175018177E-02 0.500000000E-03 4 0.938572611E+00 0.972963519E+00 0.984833807E+00 0.987726899E+00 0.972479002E+00 5 0.973212125E-02 0.954808868E-02 0.953423164E-02 0.105229196E-01 0.270209976E-01 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -1.461799455E+06 [Reboiler Heat Duty] 1.930958445E+06 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.156227887E+02 0.263995951E+02 0.262874584E+02 0.264270616E+02 0.270630450E+02 2 0.140962069E+02 0.245428205E+02 0.251378563E+02 0.261230223E+02 0.274064162E+02 3 0.306029967E+00 0.100399719E+01 0.111637188E+01 0.129110094E+01 0.149819861E+01 4 0.276326659E-01 0.133997952E+00 0.151258303E+00 0.179746649E+00 0.216388156E+00 5 0.664605987E-03 0.564482098E-02 0.649740957E-02 0.801642881E-02 0.101756605E-01 Component K-values on stages: 6 to 10 1 0.277005780E+02 0.280875055E+02 0.282854356E+02 0.312517365E+02 0.350200936E+02 2 0.284057649E+02 0.289645514E+02 0.292647994E+02 0.329508465E+02 0.373670960E+02 3 0.165796328E+01 0.174868952E+01 0.180419259E+01 0.244029342E+01 0.335395754E+01 4 0.246383913E+00 0.264000806E+00 0.274712017E+00 0.411000806E+00 0.633657883E+00 5 0.120795521E-01 0.132475258E-01 0.139581709E-01 0.242650852E-01 0.444561886E-01 Component K-values on stages: 11 to 15 1 0.377213059E+02 0.389260635E+02 0.393573697E+02 0.395098273E+02 0.397246306E+02 2 0.404092733E+02 0.417438419E+02 0.422186939E+02 0.423856942E+02 0.426129308E+02 3 0.410574475E+01 0.447652924E+01 0.461564787E+01 0.466559843E+01 0.473468334E+01 4 0.838618664E+00 0.946552173E+00 0.988193266E+00 0.100324640E+01 0.102341965E+01 5 0.661960034E-01 0.787405037E-01 0.837725922E-01 0.856128274E-01 0.880256960E-01 [Molecular weights] 1 44.097 2 42.080 3 78.114 4 120.194 5 162.264 [Feed stream 1] 8 Stage Number 5.6246820808421E-02 Flow rate 3.6315000000000E+02 Temperature [K] 1.8698607401200E+05 Pressure [Pa] -2.6054522527603E+07 Enthalpy [J/kmol] -5.6248116281965E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.2140943440372E-02 Mole fraction of component 1 2.0322628512701E-03 Mole fraction of component 2 4.9965228493754E-01 Mole fraction of component 3 4.6340694338759E-01 Mole fraction of component 4 1.2767565383224E-02 Mole fraction of component 5 5.6246820808421E-02 Flow rate 2.2140943440372E-02 Mole fraction of component 1 2.0322628512701E-03 Mole fraction of component 2 4.9965228493754E-01 Mole fraction of component 3 4.6340694338759E-01 Mole fraction of component 4 1.2767565383224E-02 Mole fraction of component 5 9.7862154582994E+01 Molar mass 8.0004803363525E+02 Density 2.9526025813995E-04 Viscosity 1.1550758214272E-01 Thermal conductivity 1.9857050953034E+05 Heat capacity 1.9959416665075E-02 Surface tension [Reflashed Feed stream 1] 8 Stage Number 5.6246820808421E-02 Flow rate 3.6315450842381E+02 Temperature [K] 1.7500000000000E+05 Pressure [Pa] -2.6054522527603E+07 Enthalpy [J/kmol] -5.6244064584541E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.2140943440372E-02 Mole fraction of component 1 2.0322628512701E-03 Mole fraction of component 2 4.9965228493754E-01 Mole fraction of component 3 4.6340694338759E-01 Mole fraction of component 4 1.2767565383224E-02 Mole fraction of component 5 5.6246820808421E-02 Flow rate 2.2140943440372E-02 Mole fraction of component 1 2.0322628512701E-03 Mole fraction of component 2 4.9965228493754E-01 Mole fraction of component 3 4.6340694338759E-01 Mole fraction of component 4 1.2767565383224E-02 Mole fraction of component 5 9.7862154582994E+01 Molar mass 8.0002574794211E+02 Density 2.9524843960600E-04 Viscosity 1.1550640446938E-01 Thermal conductivity 1.9857287759893E+05 Heat capacity 1.9958907590893E-02 Surface tension [Top product] 1 Stage Number 2.9669898225424E-02 Flow rate 3.3186661093361E+02 Temperature [K] 1.7500000000000E+05 Pressure [Pa] -2.7684904417314E+07 Enthalpy [J/kmol] -7.6539014860144E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 4.1973776544216E-02 Mole fraction of component 1 3.8526699202640E-03 Mole fraction of component 2 9.4676981574697E-01 Mole fraction of component 3 7.4037377878006E-03 Mole fraction of component 4 1.0965034085530E-13 Mole fraction of component 5 2.9669898225424E-02 Flow rate 4.1973776544216E-02 Mole fraction of component 1 3.8526699202640E-03 Mole fraction of component 2 9.4676981574697E-01 Mole fraction of component 3 7.4037377878006E-03 Mole fraction of component 4 1.0965034085530E-13 Mole fraction of component 5 7.6858897571957E+01 Molar mass 8.2185297584845E+02 Density 3.6872867213740E-04 Viscosity 1.3039017879200E-01 Thermal conductivity 1.4480967523929E+05 Heat capacity 2.2942547005408E-02 Surface tension [Bottom product] 15 Stage Number 2.6576922582997E-02 Flow rate 4.4914049408602E+02 Temperature [K] 1.7500000000000E+05 Pressure [Pa] -6.5815285062966E+06 Enthalpy [J/kmol] -3.7181507419028E+03 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.1234474607148E-13 Mole fraction of component 1 1.1814626638774E-14 Mole fraction of component 2 5.0000000000030E-04 Mole fraction of component 3 9.7247900236523E-01 Mole fraction of component 4 2.7020997635139E-02 Mole fraction of component 5 2.6576922582997E-02 Flow rate 2.1234474607148E-13 Mole fraction of component 1 1.1814626638774E-14 Mole fraction of component 2 5.0000000000030E-04 Mole fraction of component 3 9.7247900236523E-01 Mole fraction of component 4 2.7020997635139E-02 Mole fraction of component 5 1.2130973381170E+02 Molar mass 7.2064902988553E+02 Density 1.8756055280147E-04 Viscosity 9.4356374911436E-02 Thermal conductivity 2.8781101382293E+05 Heat capacity 1.2929857954055E-02 Surface tension [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stagedݽt@%Aw@Ńw@tw@^|Cx@ a@x@uJx@q#x@uւy@Z/rz@Fu:{@44{@Ƃ{@ }U:|@̽v?|@"Pressure profile.Pressure at each stage\A\A\A\A\A\A\A\A\A\A\A\A\A\A\A(Vapour Flow profile4Vapour Flow at each stageMs~=@ݤq\E@dE@wE@D@"zD@[,fD@[lbOD@eZxG@_NG@GH@@g6]@ꕲ q ^@.Vapour Density profile:Vapour Density at each stageHi6/ @e%-@>@B;@aI@mP]@8 "5m@kPp@VU@,;@쟇@ZHv@hs@KԲ@ixJ@2Vapour Viscosity profile>Vapour Viscosity at each stage|a>}۷>q+>͹]>Uz=>FR>;[>8K2{c>1p>9i+>1&@ټ>Xz>n:_>V>B3 X>:Vapour Heat capacity profileFVapour Heat capacity at each stage|a2U0T@ۊeY@y)Z@Ӽ[@/$)]@{P;^@`vO^@%*_@U0*a@x $(~e@W[i@ok@_Lxl@Onl@ l@HVapour Thermal conductivity profileTVapour Thermal conductivity at each stage,&I?zԒ3?B5?uN e??zZE?u(v?B" ?$Z?P:`?Ǜ>3o?Z>˖?m?} _#?ejl ?4Liquid Moleweight profile@Liquid Moleweight at each stage476S@lIFT@?U@GrV@ 0W@N ^X@( Y@<,ԚZY@ףp= [@I.!\@ڊe]@tF]@,C^@+ $^@S^@.Liquid Density profile:Liquid Density at each stageҮ@W@Zӧ@s{@T@&䃞3@:"@6;N@]F@lxz%@Hz.ņ@7A`嘆@@ǘ@x&1@2Liquid Viscosity profile>Liquid Viscosity at each stage %=*8?! p|1?9T1?0)1?0?~C0?[0?o /?bl.?T,,?!W˃+?RB*?Dv*?,;B*?_9I}(?:Liquid Heat capacity profileFLiquid Heat capacity at each stageHrb@tFc@,eX#e@ rf@vh@޾i@gffffNj@j@(\m@:=p@Dl2q@Qkwq@'q@Yq@"q@:Liquid Thermal cond. profileFLiquid Thermal cond. at each stage\F?_|r^?ne.?HA?y%/|?U?P:?-pힻ?? 'i?g:??7RK?4?q 2-? Q3'?0Surface tension profile<Surface tension at each stage>Tw@~?kɯ8?d ֒?";=R?cЦvȑ?85*h?Ҿ5?3)1?EcP(?e5V?W~?ޥܖ+0?etz?W nz? 1 Converged 1 Iterations QChemSep (TM) - COL2 6.90 Copyright (c) 1988-2012 Harry Kooijman and Ross Taylor License: 2100- 6 LITE free license Build: 6494e2b69d23 Checking data file C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_A_F~1.SEP Cape Open unit name: C1 Cape-Open unit id: CS_A_F94_1CCE244_725F3F40 Cape-Open run level: normal Cape open Initialized Cape Open Thermodynamic-properties disabled Reading configuration Reading component property libraries Warning! Fuller diffusion volume estimated (p-diisopropylbenzene) Ignoring all warnings User choice: Ignore Reading thermodynamic property options Reading physical property options Reading thermodynamic property data Reading specifications Reading reaction data Checking Component Data 74-98-6 Propane 115-07-1 Propylene 71-43-2 Benzene 98-82-8 Cumene 100-18-5 p-diisopropylbenzene * No class * Missing STboil * Missing Cp gas 1 * Missing V-Tc * Missing L-viscosity * Missing L-Cp * Missing L-Tc * Missing L-density Determining feed conditions Solving TP flash Possible trivial solution Run level: Initialization Reading initial temperature profiles Reading initial composition profiles Init 63 milliseconds Run level: Complete model Iteration log(Err/Tol) 0 0.6533 1 -2.1647 Run level: Report Convergence obtained in 1 iterations Time 31 milliseconds FixMem driver done run time: 0.16 seconds Using: C:\Program Files\ChemSepL6v90\bin\co-col2.exe CAPE-OPEN thermo-properties were disabled. All calculation methods have been determined by ChemSep. See output report or graphical user interface for more information. L#ZI not all ports are connected" GUIArguments UseCOSEThermoUseCOSEDiffusionCoefficientsUsePerturbedDerivativesOnlyUsePerturbed_ddXSuppressWarningsRelativePerturbationTemperatureRelativePerturbationPressurePerturbationComposition InletReflash OutletFlash!UseOnlyKValuesAndEnthalpyFromCOSERestartDataAvailableOmitStageFromPortNameWilsonEstimateLogPropertyCalls EnergyPortsUseInitialGuessTemperature profilePressure profileVapour Flow profileLiquid Flow profileDuties profileVapour Moleweight profileVapour Density profileVapour Viscosity profileVapour Heat capacity profile#Vapour Thermal conductivity profileLiquid Moleweight profileLiquid Density profileLiquid Viscosity profileLiquid Heat capacity profileLiquid Thermal cond. profileSurface tension profile Feed1{split}_stage8 TopProduct BottomProduct @ @0@@ @ @ @(@ @(@$@,@@@@@@@@$@@(@@(@ @(@ @ @ @,@$@@@$@@(@ @,@ @ @,@ @$@0@,@4@@0@@2@@2@$@2@(@0@(@(@(@(@ @(@$@4@,@0@@ 4@,@0@ 4@,@0@4@,@0@ 4@,@0@ 4@,@0@ ,@0@  ,@0@VUUUUU@)@C2ChemSep Unit OperationqeWCXcdCSUO4~[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_B_F~1.sep Title=ChemSep CO Unit Operation "C2" in COFE Flowsheet User=Harry Date=2012-02-03 Time=08:21:33 [Cape-Open] unitname=C2 CO_ID=CS_B_F94_1CCE244_7261B040 5 components Propane 74-98-6 44.0970001221 Mw Propylene 115-07-1 42.07970047 Mw Benzene 71-43-2 78.1139984131 Mw Cumene 98-82-8 120.194000244 Mw p-diisopropylbenzene 100-18-5 162.27130127 Mw 1 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=TRUE WilsonEstimate=TRUE Status= 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=C Flow=kmol/h Mass flow=kg/s Pressure=bar Heat=MW Enthalpy=kJ/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=deg Velocity=m/s Surface tension=dyn/cm Density=kg/m3 Molar density=kmol/m3 Viscosity=Pa.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=1e-8 m2/s Interaction parameter=J/mol Time=s [Components] 5 67 3 Library Offset, Index DT=2012-01-31,09:17:24 CHK=60240 CAS=74-98-6 CID=Propane Name=Propane Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 61 202 Library Offset, Index DT=2012-01-31,09:17:24 CHK=29371 CAS=115-07-1 CID=Propylene Name=Propylene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 125 501 Library Offset, Index DT=2012-01-31,09:17:24 CHK=23428 CAS=71-43-2 CID=Benzene Name=Benzene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 163 510 Library Offset, Index DT=2012-01-31,09:17:24 CHK=5750 CAS=98-82-8 CID=Cumene Name=Cumene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 1 544 Library Offset, Index DT=2011-12-15,01:03:44 CHK=53139 CAS=100-18-5 CID=p-diisopropylbenzene Name=p-diisopropylbenzene Lib=h:\downloads\lyubenaichem2011\diisopropylbenzene.pcd [Operation] 2 Operation Column 1 Operation kind Simple Distillation 1 Condenser Total (Liquid product) 1 Reboiler Partial (Liquid product) 20 Stages 1 Feed stages 0 Sidestream stages F=12 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 1 K model Raoult's law * * Activity coefficient * * Wilson model * * UNIQUAC model * 3 Equation of State Cubic 5 Cubic EOS Peng-Robinson 76 * Virial EOS * 1 Vapour pressure Antoine 0 Henry's law * Henry's default * [Enthalpy] 3 Enthalpy Excess 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 0 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Heaters/Coolers] 0 Number 0 Column duty Qcolumn 2 First stage 19 Last stage 0 Qcolumn lost to surroundings [Efficiencies] 1 Default efficiency 0 Number [Pressures] 1 Column pressure Constant pressure 100000 Condenser pressure 100000 Top pressure * Pressure Drop * Bottom pressure [Feeds] 1 Number 2 Feed state p & VF 12 Stage Feed1{split} 423.744505067 Temperature 100000 Pressure 0.167685260499 Vapour fraction 5 componentflows 5.64346987725e-015 Component 1 flow 3.13996417526e-016 Component 2 flow 1.32884612915e-005 Component 3 flow 0.0258454991595 Component 4 flow 0.000718134962264 Component 5 flow [Condenser] 7 Type Mole fraction of a component 0.999 Value Qcondenser 4 1st comp. * Type * * Initialization guess [Reboiler] 11 Type Flexible 0.99 Value Qreboiler x13/x1-(0.63) RR=0.63 * Type * * Initialization guess [Monitored Variables] * [Solve options] 3 Initialization Old Results 2 Method 2-pass constant H first 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 30 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 y1 x2 y2 StringGrid=StringGrid3 1 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 3 ComboBox=ComboBox23 4 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram Cumene - p-diisopropylbenzene Xlabel X Cumene/(Cumene+p-diisopropylbenzene) Ylabel Y Cumene/(Cumene+p-diisopropylbenzene) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 3 ComboBox=ComboBox76 4 ComboBox=ComboBox77 0 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Title ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 12 Edit=Edit6 Edit=Edit7 c:\program files\chemsepl6v84\pcd\chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 6 7 Identifier L# File Loc. CAS SMILES Name Propane 3 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 67 74-98-6 CCC Propane Propylene 202 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 61 115-07-1 C=CC Propylene Benzene 501 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 125 71-43-2 c1ccccc1 Benzene Cumene 510 c:\program files\chemsepl6v84\pcd\chemsep1.pcd 163 98-82-8 c1(C(C)C)ccccc1 Cumene p-diisopropylbenzene 544 h:\downloads\lyubenaichem2011\diisopropylbenzene.pcd 1 100-18-5 c1(C(C)C)ccc(C(C)C)cc1 p-diisopropylbenzene 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 1 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 424.8954365 1.000000000E+05 2.587137003E-02 1.629896312E-02 -1.574471322E+06 2 425.1264928 1.000000000E+05 4.217033315E-02 1.620592557E-02 0.000000000E+00 3 425.6776218 1.000000000E+05 4.207729560E-02 1.587200949E-02 0.000000000E+00 4 427.5444051 1.000000000E+05 4.174337953E-02 1.502315314E-02 0.000000000E+00 5 432.6594259 1.000000000E+05 4.089452317E-02 1.379265758E-02 0.000000000E+00 6 441.6863567 1.000000000E+05 3.966402762E-02 1.301234419E-02 0.000000000E+00 7 450.8560565 1.000000000E+05 3.888371423E-02 1.291574097E-02 0.000000000E+00 8 456.8183809 1.000000000E+05 3.878711100E-02 1.306049987E-02 0.000000000E+00 9 459.8421598 1.000000000E+05 3.893186990E-02 1.318274005E-02 0.000000000E+00 10 461.2152999 1.000000000E+05 3.905411009E-02 1.324826348E-02 0.000000000E+00 11 461.8110095 1.000000000E+05 3.911963351E-02 1.359436516E-02 0.000000000E+00 12 465.0715327 1.000000000E+05 3.500917701E-02 3.855003873E-02 0.000000000E+00 13 492.0631964 1.000000000E+05 3.784448618E-02 4.928525453E-02 0.000000000E+00 14 501.2088787 1.000000000E+05 4.857970198E-02 5.525686855E-02 0.000000000E+00 15 503.2160834 1.000000000E+05 5.455131600E-02 5.681203422E-02 0.000000000E+00 16 503.6121094 1.000000000E+05 5.610648167E-02 5.713110050E-02 0.000000000E+00 17 503.6885884 1.000000000E+05 5.642554794E-02 5.719319934E-02 0.000000000E+00 18 503.7032964 1.000000000E+05 5.648764679E-02 5.720515991E-02 0.000000000E+00 19 503.7061228 1.000000000E+05 5.649960735E-02 5.720745895E-02 0.000000000E+00 20 503.7066658 1.000000000E+05 5.650190640E-02 7.055525506E-04 1.420250928E+06 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.1313913E+08 -0.1313913E+08 -0.2448286E+05 -0.2448286E+05 2 0.2419687E+08 -0.1299379E+08 0.6714644E+05 -0.2410631E+05 3 0.2433540E+08 -0.1254749E+08 0.6755981E+05 -0.2305624E+05 4 0.2480370E+08 -0.1105265E+08 0.6894120E+05 -0.2009948E+05 5 0.2612816E+08 -0.7145621E+07 0.7272821E+05 -0.1349628E+05 6 0.2864023E+08 -0.8087335E+06 0.7974021E+05 -0.3717406E+04 7 0.3147900E+08 0.5077414E+07 0.8748856E+05 0.5212848E+04 8 0.3351945E+08 0.8683283E+07 0.9293988E+05 0.1073916E+05 9 0.3462336E+08 0.1045882E+08 0.9584412E+05 0.1348393E+05 10 0.3514150E+08 0.1125473E+08 0.9719579E+05 0.1471954E+05 11 0.3536970E+08 0.1159813E+08 0.9778872E+05 0.1525363E+05 12 0.3665939E+08 0.1345750E+08 0.1011008E+06 0.1815603E+05 13 0.5060268E+08 0.2800855E+08 0.1334663E+06 0.4113888E+05 14 0.5715667E+08 0.3274032E+08 0.1454982E+06 0.4836538E+05 15 0.5875885E+08 0.3377221E+08 0.1476524E+06 0.4981754E+05 16 0.5908253E+08 0.3397559E+08 0.1479309E+06 0.5007545E+05 17 0.5914533E+08 0.3401486E+08 0.1479547E+06 0.5011957E+05 18 0.5915742E+08 0.3402241E+08 0.1479534E+06 0.5012696E+05 19 0.5915975E+08 0.3402386E+08 0.1479521E+06 0.5012816E+05 20 0.5916019E+08 0.3402414E+08 0.1479516E+06 0.5012836E+05 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.1200658E+03 0.3398813E+01 0.8745703E-05 0.2201678E+06 0.1988014E-01 2 0.1201928E+03 0.3400560E+01 0.8744307E-05 0.2205694E+06 0.1989606E-01 3 0.1202687E+03 0.3398300E+01 0.8747917E-05 0.2209712E+06 0.1993923E-01 4 0.1205168E+03 0.3390443E+01 0.8759386E-05 0.2223062E+06 0.2008302E-01 5 0.1212992E+03 0.3372111E+01 0.8779027E-05 0.2261810E+06 0.2045193E-01 6 0.1231040E+03 0.3352340E+01 0.8766343E-05 0.2339392E+06 0.2099542E-01 7 0.1256053E+03 0.3350888E+01 0.8682192E-05 0.2433163E+06 0.2136826E-01 8 0.1276644E+03 0.3361369E+01 0.8584231E-05 0.2504116E+06 0.2148854E-01 9 0.1288569E+03 0.3370457E+01 0.8520651E-05 0.2543588E+06 0.2150624E-01 10 0.1294338E+03 0.3375468E+01 0.8488603E-05 0.2562356E+06 0.2150374E-01 11 0.1296912E+03 0.3377817E+01 0.8474076E-05 0.2570667E+06 0.2150053E-01 12 0.1311848E+03 0.3392766E+01 0.8387688E-05 0.2618216E+06 0.2145898E-01 13 0.1497891E+03 0.3661418E+01 0.7236332E-05 0.3167097E+06 0.1910302E-01 14 0.1593134E+03 0.3823169E+01 0.6686088E-05 0.3436327E+06 0.1721006E-01 15 0.1616718E+03 0.3864291E+01 0.6556655E-05 0.3502572E+06 0.1669895E-01 16 0.1621493E+03 0.3872655E+01 0.6530788E-05 0.3515968E+06 0.1659372E-01 17 0.1622419E+03 0.3874280E+01 0.6525780E-05 0.3518568E+06 0.1657323E-01 18 0.1622598E+03 0.3874592E+01 0.6524817E-05 0.3519069E+06 0.1656929E-01 19 0.1622632E+03 0.3874653E+01 0.6524631E-05 0.3519165E+06 0.1656853E-01 20 0.1622639E+03 0.3874664E+01 0.6524596E-05 0.3519183E+06 0.1656838E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.1201928E+03 0.7434532E+03 0.2471895E-03 0.2710187E+06 0.9778133E-01 0.1474813E-01 2 0.1203897E+03 0.7434932E+03 0.2428858E-03 0.2716355E+06 0.9775529E-01 0.1478504E-01 3 0.1210449E+03 0.7439243E+03 0.2281183E-03 0.2735753E+06 0.9772147E-01 0.1494525E-01 4 0.1232045E+03 0.7452351E+03 0.1855683E-03 0.2800051E+06 0.9760452E-01 0.1548179E-01 5 0.1285645E+03 0.7476249E+03 0.1116606E-03 0.2962799E+06 0.9724492E-01 0.1685752E-01 6 0.1363663E+03 0.7487910E+03 0.5405923E-04 0.3209754E+06 0.9647475E-01 0.1899370E-01 7 0.1426305E+03 0.7474548E+03 0.3069585E-04 0.3419730E+06 0.9552517E-01 0.2085687E-01 8 0.1460194E+03 0.7457050E+03 0.2279307E-04 0.3539144E+06 0.9482279E-01 0.2193624E-01 9 0.1475693E+03 0.7446206E+03 0.1994250E-04 0.3595424E+06 0.9444214E-01 0.2245015E-01 10 0.1482397E+03 0.7440907E+03 0.1883355E-04 0.3620123E+06 0.9426398E-01 0.2267677E-01 11 0.1485243E+03 0.7438540E+03 0.1838356E-04 0.3630679E+06 0.9418567E-01 0.2277383E-01 12 0.1500174E+03 0.7424885E+03 0.1621264E-04 0.3686785E+06 0.9374608E-01 0.2329133E-01 13 0.1593556E+03 0.7281405E+03 0.7872084E-05 0.4070448E+06 0.8944570E-01 0.2695336E-01 14 0.1616794E+03 0.7224713E+03 0.6760480E-05 0.4176564E+06 0.8773386E-01 0.2801910E-01 15 0.1621507E+03 0.7211900E+03 0.6569005E-05 0.4198647E+06 0.8734144E-01 0.2824512E-01 16 0.1622422E+03 0.7209358E+03 0.6533087E-05 0.4202957E+06 0.8726332E-01 0.2828942E-01 17 0.1622598E+03 0.7208867E+03 0.6526219E-05 0.4203787E+06 0.8724821E-01 0.2829797E-01 18 0.1622632E+03 0.7208772E+03 0.6524901E-05 0.4203947E+06 0.8724530E-01 0.2829961E-01 19 0.1622639E+03 0.7208754E+03 0.6524648E-05 0.4203978E+06 0.8724474E-01 0.2829993E-01 20 0.1622640E+03 0.7208750E+03 0.6524599E-05 0.4203984E+06 0.8724463E-01 0.2829999E-01 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.895575068E-11 0.218135718E-12 0.136167838E-12 0.136455453E-12 0.139221617E-12 2 0.534880161E-12 0.121368299E-13 0.756843865E-14 0.758736301E-14 0.774144858E-14 3 0.309603275E-02 0.513635779E-03 0.348477006E-03 0.339974197E-03 0.344589634E-03 4 0.996854451E+00 0.999000000E+00 0.997527761E+00 0.991646430E+00 0.973039491E+00 5 0.495160965E-04 0.486364221E-03 0.212376217E-02 0.801359630E-02 0.266159191E-01 Component Mole fractions on stages: 6 to 10 1 0.143461003E-12 0.146306466E-12 0.146685231E-12 0.146156163E-12 0.145705525E-12 2 0.797748600E-14 0.813584445E-14 0.815685319E-14 0.812737029E-14 0.810228497E-14 3 0.352065159E-03 0.355859570E-03 0.354613522E-03 0.352190933E-03 0.350566978E-03 4 0.930125703E+00 0.870662934E+00 0.821720530E+00 0.793379485E+00 0.779669662E+00 5 0.695222321E-01 0.128981206E+00 0.177924856E+00 0.206268324E+00 0.219979771E+00 Component Mole fractions on stages: 11 to 15 1 0.145463720E-12 0.187624622E-13 0.465518401E-15 0.115033433E-16 0.283811714E-18 2 0.808883013E-14 0.979164498E-15 0.226321737E-16 0.520987924E-18 0.119656076E-19 3 0.349746307E-03 0.180622459E-03 0.146132064E-04 0.772823207E-06 0.357799073E-07 4 0.773553197E+00 0.738387606E+00 0.296497817E+00 0.701342698E-01 0.140760433E-01 5 0.226097057E+00 0.261431771E+00 0.703487569E+00 0.929864957E+00 0.985923921E+00 Component Mole fractions on stages: 16 to 20 1 0.699975413E-20 0.172625349E-21 0.425716542E-23 0.104986176E-24 0.000000000E+00 2 0.264428151E-21 0.110221300E-23 0.851221000E-24 0.713286000E-24 0.348701350E-23 3 0.160996592E-08 0.720383238E-10 0.321989086E-11 0.143885931E-12 0.642613128E-14 4 0.272754205E-02 0.524883115E-03 0.100866191E-03 0.193712781E-04 0.371294868E-05 5 0.997272456E+00 0.999475117E+00 0.999899134E+00 0.999980629E+00 0.999996287E+00 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.218135718E-12 0.531314760E-14 0.331664839E-14 0.332365476E-14 0.339102927E-14 2 0.121368299E-13 0.275393919E-15 0.171733560E-15 0.172163014E-15 0.175659274E-15 3 0.513635779E-03 0.848151939E-04 0.569058790E-04 0.534752901E-04 0.490014993E-04 4 0.999000000E+00 0.995177457E+00 0.979660112E+00 0.928332903E+00 0.800935776E+00 5 0.486364221E-03 0.473772753E-02 0.202829820E-01 0.716136220E-01 0.199015223E+00 Component Mole fractions on stages: 6 to 10 1 0.349429218E-14 0.356359357E-14 0.357282356E-14 0.355993825E-14 0.354895970E-14 2 0.181015342E-15 0.184608321E-15 0.185085250E-15 0.184416323E-15 0.183846999E-15 3 0.421661571E-04 0.360778938E-04 0.323869906E-04 0.305414563E-04 0.297009523E-04 4 0.615500938E+00 0.466614093E+00 0.386068548E+00 0.349229836E+00 0.333297938E+00 5 0.384456896E+00 0.533349830E+00 0.613899065E+00 0.650739622E+00 0.666672362E+00 Component Mole fractions on stages: 11 to 15 1 0.354306949E-14 0.456998365E-15 0.113386650E-16 0.280187837E-18 0.691282370E-20 2 0.183541670E-15 0.222179695E-16 0.513541820E-18 0.118216697E-19 0.269744077E-21 3 0.293349990E-04 0.143457519E-04 0.761759708E-06 0.353230482E-07 0.158997165E-08 4 0.326533079E+00 0.291071252E+00 0.691302592E-01 0.138963210E-01 0.269367727E-02 5 0.673437586E+00 0.708914402E+00 0.930868979E+00 0.986103644E+00 0.997306321E+00 Component Mole fractions on stages: 16 to 20 1 0.170493476E-21 0.420464852E-23 0.103692083E-24 0.000000000E+00 0.000000000E+00 2 0.732739675E-23 0.282072052E-23 0.231684400E-24 0.286327700E-23 0.365023878E-21 3 0.711486749E-10 0.318017281E-11 0.142114780E-12 0.635037422E-14 0.283613542E-15 4 0.518409662E-03 0.996305668E-04 0.191410479E-04 0.367584546E-05 0.704553307E-06 5 0.999481590E+00 0.999900369E+00 0.999980859E+00 0.999996324E+00 0.999999295E+00 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 16 to 20 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 5 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -1.574471322E+06 [Reboiler Heat Duty] 1.420250928E+06 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 2 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 3 0.602768125E+01 0.605594063E+01 0.612374350E+01 0.635759426E+01 0.703222633E+01 4 0.997852304E+00 0.100384107E+01 0.101823862E+01 0.106820132E+01 0.121487830E+01 5 0.101808674E+00 0.102657702E+00 0.104706604E+00 0.111900447E+00 0.133738106E+00 Component K-values on stages: 6 to 10 1 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 2 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 3 0.834947226E+01 0.986364594E+01 0.109492582E+02 0.115315697E+02 0.118032235E+02 4 0.151116862E+01 0.186591650E+01 0.212843168E+01 0.227179755E+01 0.233925739E+01 5 0.180832319E+00 0.241832282E+00 0.289827541E+00 0.316975203E+00 0.329966838E+00 Component K-values on stages: 11 to 15 1 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 2 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 3 0.119224925E+02 0.125906583E+02 0.191834857E+02 0.218787236E+02 0.225034877E+02 4 0.236898877E+01 0.253679331E+01 0.428897303E+01 0.504696675E+01 0.522558637E+01 5 0.335735727E+00 0.368777627E+00 0.755732101E+00 0.942968788E+00 0.988586856E+00 Component K-values on stages: 16 to 20 1 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 0.410558410E+02 2 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 0.440708036E+02 3 0.226281926E+02 0.226523299E+02 0.226569739E+02 0.226578664E+02 0.226580379E+02 4 0.526136424E+01 0.526829398E+01 0.526962743E+01 0.526988370E+01 0.526993294E+01 5 0.997789720E+00 0.999574705E+00 0.999918273E+00 0.999984305E+00 0.999996991E+00 [Molecular weights] 1 44.097 2 42.080 3 78.114 4 120.194 5 162.264 [Feed stream 1] 12 Stage Number 2.6576922583061E-02 Flow rate 4.2604496983009E+02 Temperature [K] 1.0000000000000E+05 Pressure [Pa] -6.0842619487648E+06 Enthalpy [J/kmol] 4.5509322328534E+04 Entropy [J/kmol/K] 1.6768526049900E-01 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.1234474607104E-13 Mole fraction of component 1 1.1814626638756E-14 Mole fraction of component 2 4.9999999999884E-04 Mole fraction of component 3 9.7247900236472E-01 Mole fraction of component 4 2.7020997635057E-02 Mole fraction of component 5 4.4565581866024E-03 Flow rate 1.1297456389693E-12 Mole fraction of component 1 6.3325056607819E-14 Mole fraction of component 2 1.6523532118219E-03 Mole fraction of component 3 9.9497549078037E-01 Mole fraction of component 4 3.3721560066160E-03 Mole fraction of component 5 2.2120364396459E-02 Flow rate 2.7517294566137E-14 Mole fraction of component 1 1.4368936642145E-15 Mole fraction of component 2 2.6783703937441E-04 Mole fraction of component 3 9.6794666687883E-01 Mole fraction of component 4 3.1785496081772E-02 Mole fraction of component 5 1.2026633584577E+02 Molar mass 3.3953036259006E+00 Density 8.7518783235822E-06 Viscosity 1.9969039910535E-02 Thermal conductivity 2.2110896356762E+05 Heat capacity 1.2151994571400E+02 Molar mass 7.4427702038337E+02 Density 2.1783073312712E-04 Viscosity 9.7705129146622E-02 Thermal conductivity 2.7496567755186E+05 Heat capacity 1.5068022318976E-02 Surface tension [Reflashed Feed stream 1] 12 Stage Number 2.6576922583061E-02 Flow rate 4.2604496983009E+02 Temperature [K] 1.0000000000000E+05 Pressure [Pa] -6.0842619487648E+06 Enthalpy [J/kmol] 4.5509322320397E+04 Entropy [J/kmol/K] 1.6768526035192E-01 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.1234474607104E-13 Mole fraction of component 1 1.1814626638756E-14 Mole fraction of component 2 4.9999999999884E-04 Mole fraction of component 3 9.7247900236472E-01 Mole fraction of component 4 2.7020997635057E-02 Mole fraction of component 5 4.4565581826935E-03 Flow rate 1.1297456670002E-12 Mole fraction of component 1 6.3325058179467E-14 Mole fraction of component 2 1.6523532355224E-03 Mole fraction of component 3 9.9497549080893E-01 Mole fraction of component 4 3.3721559543542E-03 Mole fraction of component 5 2.2120364400368E-02 Flow rate 2.7517294453824E-14 Mole fraction of component 1 1.4368936583599E-15 Mole fraction of component 2 2.6783704155211E-04 Mole fraction of component 3 9.6794666700880E-01 Mole fraction of component 4 3.1785495949618E-02 Mole fraction of component 5 1.2026633584257E+02 Molar mass 3.3953036258104E+00 Density 8.7518783238545E-06 Viscosity 1.9969039910977E-02 Thermal conductivity 2.2110896356080E+05 Heat capacity 1.2151994570834E+02 Molar mass 7.4427702037516E+02 Density 2.1783073323605E-04 Viscosity 9.7705129146179E-02 Thermal conductivity 2.7496567753774E+05 Heat capacity 1.5068022317165E-02 Surface tension [Top product] 1 Stage Number 2.5871370032435E-02 Flow rate 4.2489543646521E+02 Temperature [K] 1.0000000000000E+05 Pressure [Pa] -1.3139125235371E+07 Enthalpy [J/kmol] -2.4482858329506E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.1813571794840E-13 Mole fraction of component 1 1.2136829888864E-14 Mole fraction of component 2 5.1363577865661E-04 Mole fraction of component 3 9.9899999999994E-01 Mole fraction of component 4 4.8636422111303E-04 Mole fraction of component 5 2.5871370032435E-02 Flow rate 2.1813571794840E-13 Mole fraction of component 1 1.2136829888864E-14 Mole fraction of component 2 5.1363577865661E-04 Mole fraction of component 3 9.9899999999994E-01 Mole fraction of component 4 4.8636422111303E-04 Mole fraction of component 5 1.2019284779595E+02 Molar mass 7.4345319846276E+02 Density 2.4718951779887E-04 Viscosity 9.7781330031453E-02 Thermal conductivity 2.7101871690031E+05 Heat capacity 1.4748127529573E-02 Surface tension [Bottom product] 20 Stage Number 7.0555255062663E-04 Flow rate 5.0370666576826E+02 Temperature [K] 1.0000000000000E+05 Pressure [Pa] 3.4024137781302E+07 Enthalpy [J/kmol] 5.0128355581899E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 0.0000000000000E+00 Mole fraction of component 1 3.6502387790719E-22 Mole fraction of component 2 2.8361354191965E-16 Mole fraction of component 3 7.0455330728154E-07 Mole fraction of component 4 9.9999929544774E-01 Mole fraction of component 5 7.0555255062663E-04 Flow rate 0.0000000000000E+00 Mole fraction of component 1 3.6502387790719E-22 Mole fraction of component 2 2.8361354191965E-16 Mole fraction of component 3 7.0455330728154E-07 Mole fraction of component 4 9.9999929544774E-01 Mole fraction of component 5 1.6226397792797E+02 Molar mass 7.2087503365408E+02 Density 6.5245988824013E-06 Viscosity 8.7244634228285E-02 Thermal conductivity 4.2039836492090E+05 Heat capacity 2.8299985973750E-02 Surface tension [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stageQ29Sz@rPz@ךz@iD⵸z@**, {@?)Q{@tLh-|@|@|y|@PNq|@|@x$}@s:~@L1WS@Vus@093y@{&Eu{@Pֹ@{@\kGL{@:C̀N{@"Pressure profile.Pressure at each stagej@j@j@j@j@j@j@j@j@j@j@j@j@j@j@j@j@j@j@j@(Vapour Flow profile4Vapour Flow at each stage59@\VzE@} E@x'D@U8rD@6gC@nBqC@2 dC@;PLGwC@wUC@Tz&PC@V,A@B@cê3JH@z΅FK@#0 L@Zx6L@R5k>L@6"?L@ x>@L@(Liquid Flow profile4Liquid Flow at each stage1؈L0@gĉ40@ "x/@ 3v .@ 6ו+@HQ*@)@*@֔]*@Ed*@)XP0+@qJgFC@dn8H@{ϒK@gL@ǐL@StL@=BL@L@M?Duties profile*Duties at each stagenRG8shګ5A4Vapour Moleweight profile@Vapour Moleweight at each stage46^@ΪV ^@|a2^@N@!^@&S^@-^@46Vapour Viscosity at each stage;ɇDPW>^%gV>ﺎX>M0Kب^>EH4i>ggeb>a75>z>9[}>ddwH>#|>>JY>#w! >0['>] Vad>5a_>UqG ]>Q]>C_J]>:Vapour Heat capacity profileFVapour Heat capacity at each stage^k@JY8k@k@!Ack@oEl@( >m@1w-!jn@a+Mo@9#J{o@op@K4p@L F%]p@cZs@ zu@H}u@ $(~u@hsu@ u@lu@>W[u@HVapour Thermal conductivity profileTVapour Thermal conductivity at each stageSBu[?B_?j?nk?Y?)?\}?'?U?*? c$<?8W?Ȍ?r??@ r3@v@48œ@Q@ܵ|@j+@io@Y@@2Liquid Viscosity profile>Liquid Viscosity at each stagec&30?"/?Fa-?x1R(?AjE?W ? _?0w> 0*F>Hz>?F>'&# >J>a[>XXj>Gf>+'Bky_>@!^>8]>Q]>:Liquid Heat capacity profileFLiquid Heat capacity at each stage_Lp@I +p@8m4q@ZӼq@i"lxzr@L=t@!rh_u@gav@Uxv@|a2v@`vOv@`" w@m4py@QIz@ͪ=z@V/Dz@/'Fz@{PFz@ec]Fz@_Fz@:Liquid Thermal cond. profileFLiquid Thermal cond. at each stagef~2?l}?]5F?~W?% ?\#?uGiVt?m)mNF? .\-?qJ'!?fT?Kk;?SD?su?)b4\?VV?mU?2:>U?=K ٫U?U?0Surface tension profile<Surface tension at each stageѝ7D4?)zG?t'?#Jޭ괏?]C?Qs? 0ڀ[?q%tv?B),?F8?7R?xٗ?^?+F ?I?'?^Ş$?­?P'?1.? 1 Converged 1 Iterations 4ChemSep (TM) - COL2 6.90 Copyright (c) 1988-2012 Harry Kooijman and Ross Taylor License: 2100- 6 LITE free license Build: 6494e2b69d23 Checking data file C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_B_F~1.SEP Cape Open unit name: C2 Cape-Open unit id: CS_B_F94_1CCE244_7261B040 Cape-Open run level: normal Cape open Initialized Cape Open Thermodynamic-properties disabled Reading configuration Reading component property libraries Warning! Fuller diffusion volume estimated (p-diisopropylbenzene) Ignoring all warnings User choice: Ignore Reading thermodynamic property options Reading physical property options Reading thermodynamic property data Reading specifications Reading reaction data Checking Component Data 74-98-6 Propane 115-07-1 Propylene 71-43-2 Benzene 98-82-8 Cumene 100-18-5 p-diisopropylbenzene * No class * Missing STboil * Missing Cp gas 1 * Missing V-Tc * Missing L-viscosity * Missing L-Cp * Missing L-Tc * Missing L-density Determining feed conditions Solving PV flash Run level: Initialization Reading initial temperature profiles Reading initial composition profiles Init 63 milliseconds Run level: Complete model Iteration log(Err/Tol) 0 0.6759 1 -3.1703 Run level: Report Convergence obtained in 1 iterations Time 31 milliseconds FixMem driver done run time: 0.17 seconds Using: C:\Program Files\ChemSepL6v90\bin\co-col2.exe CAPE-OPEN thermo-properties were disabled. All calculation methods have been determined by ChemSep. See output report or graphical user interface for more information. f"tH not all ports are connected" GUIArguments UseCOSEThermoUseCOSEDiffusionCoefficientsUsePerturbedDerivativesOnlyUsePerturbed_ddXSuppressWarningsRelativePerturbationTemperatureRelativePerturbationPressurePerturbationComposition InletReflash OutletFlash!UseOnlyKValuesAndEnthalpyFromCOSERestartDataAvailableOmitStageFromPortNameWilsonEstimateLogPropertyCalls EnergyPortsUseInitialGuessTemperature profilePressure profileVapour Flow profileLiquid Flow profileDuties profileVapour Moleweight profileVapour Density profileVapour Viscosity profileVapour Heat capacity profile#Vapour Thermal conductivity profileLiquid Moleweight profileLiquid Density profileLiquid Viscosity profileLiquid Heat capacity profileLiquid Thermal cond. profileSurface tension profileFeed1{split}_stage12 TopProduct BottomProduct @ @0@@ @ @ @(@ @(@$@,@@@@@@@@$@@(@@(@ @(@ @ @ @,@$@@@$@@(@ @,@ @ @,@ @$@0@,@4@@0@@2@@2@$@2@(@0@(@(@(@(@ @(@$@4@,@0@@ 4@,@0@ 4@,@0@4@,@0@ 4@,@0@ 4@,@0@ ,@0@  ,@0@@*@ solving C2 Valve_141Valve - generates power from pressure difference.tQGt HՐ'aTHCOUSCOUS0002Pressure spec. Pressure drop specification typePressurePressure differencePressure differencePressurePressure differencePressure drop along the valve??O@ _BPressureValve outlet pressure?j@j@ _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last runo+++ specifications +++ Pressure: 100000 Pa +++ optional parameters +++ Pressure difference: 75000 Pa `6c8 $not all material ports are connected InletOutlet0@@@@@?@solving Valve_14 Flash TankChemSep Unit OperationqeWCXcsOCSUOs9[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_C_F~1.sep Title=ChemSep CO Unit Operation "Flash Tank" in COFE Flowsheet User=Harry Date=2012-02-03 Time=08:21:30 [Cape-Open] unitname=Flash Tank CO_ID=CS_C_F94_1CCE244_7261B040 5 components Propane 74-98-6 44.0970001221 Mw Propylene 115-07-1 42.07970047 Mw Benzene 71-43-2 78.1139984131 Mw Cumene 98-82-8 120.194000244 Mw p-diisopropylbenzene 100-18-5 162.27130127 Mw 1 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=TRUE WilsonEstimate=TRUE Status= 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=K Flow=kmol/h Mass flow=kg/s Pressure=N/m2 Heat=J/s Enthalpy=J/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=rad Velocity=m/s Surface tension=N/m Density=kg/m3 Molar density=kmol/m3 Viscosity=N/m2.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=m2/s Interaction parameter=J/mol Time=s [Components] 5 67 3 Library Offset, Index DT=2012-01-31,09:17:24 CHK=60240 CAS=74-98-6 CID=Propane Name=Propane Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 61 202 Library Offset, Index DT=2012-01-31,09:17:24 CHK=29371 CAS=115-07-1 CID=Propylene Name=Propylene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 125 501 Library Offset, Index DT=2012-01-31,09:17:24 CHK=23428 CAS=71-43-2 CID=Benzene Name=Benzene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 163 510 Library Offset, Index DT=2012-01-31,09:17:24 CHK=5750 CAS=98-82-8 CID=Cumene Name=Cumene Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 1 544 Library Offset, Index DT=2011-12-15,01:03:44 CHK=53139 CAS=100-18-5 CID=p-diisopropylbenzene Name=p-diisopropylbenzene Lib=h:\downloads\lyubenaichem2011\diisopropylbenzene.pcd [Operation] 1 Operation Flash * Operation kind * * Condenser * * Reboiler * 1 Stages 1 Feed stages 0 Sidestream stages F=1 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 4 K model DECHEMA 6 1 Activity coefficient NRTL * Wilson model * * UNIQUAC model * 3 Equation of State Cubic 5 Cubic EOS Peng-Robinson 76 * Virial EOS * 1 Vapour pressure Antoine 0 Henry's law * Henry's default * [Enthalpy] 3 Enthalpy Excess 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 0 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Property Data] [NRTL Data] i j Aij Aji aij Component Component 1 2 * * * Propane/Propylene 1 3 * * * Propane/Benzene 1 4 * * * Propane/Cumene 1 5 * * * Propane/p-diisopropylbenzene 2 3 * * * Propylene/Benzene 2 4 * * * Propylene/Cumene 2 5 * * * Propylene/p-diisopropylbenzene 3 4 8015.363 -3391.145 0.3693 Benzene/Cumene 3 5 * * * Benzene/p-diisopropylbenzene 4 5 * * * Cumene/p-diisopropylbenzene [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Feeds] 1 Number 2 Feed state p & VF 1 Stage Feed1{split-below} 359.873431468 Temperature 175000 Pressure 0.0436944049711 Vapour fraction 5 componentflows 0.00269101589516 Component 1 flow 0.00024861618842 Component 2 flow 0.0292636244676 Component 3 flow 0.0261586697129 Component 4 flow 0.000718224544328 Component 5 flow [Flash] 5 Flash type Temperature & vapour flow * Pressure 363.15 Temperature 0.00283333 Vapour flow * Liquid flow * Heat duty Q flash [Solve options] 3 Initialization Old Results 1 Method Newton's method 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 30 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 y1 x2 y2 StringGrid=StringGrid3 1 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Title ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 1 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 6 7 Identifier L# File Loc. CAS SMILES Name Propane 3 c:\cop683\pcd\chemsep1.pcd 67 74-98-6 CCC Propane Propylene 202 c:\cop683\pcd\chemsep1.pcd 61 115-07-1 C=CC Propylene Benzene 501 c:\cop683\pcd\chemsep1.pcd 125 71-43-2 c1ccccc1 Benzene Cumene 510 c:\cop683\pcd\chemsep1.pcd 163 98-82-8 c1(C(C)C)ccccc1 Cumene p-diisopropylbenzene 544 c:\cop683\pcd\diisopropylbenzene.pcd 1 100-18-5 p-diisopropylbenzene 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 0 Iterations [Feed stream 1] 0 Stage Number 5.9080150808408E-02 Flow rate 3.5907543874621E+02 Temperature [K] 1.7500000000000E+05 Pressure [Pa] -2.6359251952762E+07 Enthalpy [J/kmol] -4.6319709847125E+04 Entropy [J/kmol/K] 4.3694404971100E-02 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 4.5548561713844E-02 Mole fraction of component 1 4.2081170243834E-03 Mole fraction of component 2 4.9532074761453E-01 Mole fraction of component 3 4.4276579113229E-01 Mole fraction of component 4 1.2156782514946E-02 Mole fraction of component 5 2.5814720351762E-03 Flow rate 5.3370936912794E-01 Mole fraction of component 1 4.9623958048667E-02 Mole fraction of component 2 3.8685775148439E-01 Mole fraction of component 3 2.9781809064307E-02 Mole fraction of component 4 2.7112274700014E-05 Mole fraction of component 5 5.6498678773232E-02 Flow rate 2.3244084810147E-02 Mole fraction of component 1 2.1330291398109E-03 Mole fraction of component 2 5.0027651291840E-01 Mole fraction of component 3 4.6163537580548E-01 Mole fraction of component 4 1.2710997326159E-02 Mole fraction of component 5 5.9426143304242E+01 Molar mass 3.4835325636274E+00 Density 9.4495516805256E-06 Viscosity 2.1200407918470E-02 Thermal conductivity 9.3777379866136E+04 Heat capacity 9.7741690212821E+01 Molar mass 8.0380533623536E+02 Density 3.0553950506082E-04 Viscosity 1.1653468083556E-01 Thermal conductivity 1.9638228243230E+05 Heat capacity 2.0395567939530E-02 Surface tension [Top product] 0 Stage Number 2.8333300000000E-03 Flow rate 3.6315000000000E+02 Temperature [K] 1.8645492414872E+05 Pressure [Pa] 5.6877201015834E+06 Enthalpy [J/kmol] 2.0170577798213E+04 Entropy [J/kmol/K] 1.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 5.1020959169598E-01 Mole fraction of component 1 4.7400663543152E-02 Mole fraction of component 2 4.0933606646492E-01 Mole fraction of component 3 3.3021452553679E-02 Mole fraction of component 4 3.2225742267063E-05 Mole fraction of component 5 2.8333300000000E-03 Flow rate 5.1020959169598E-01 Mole fraction of component 1 4.7400663543152E-02 Mole fraction of component 2 4.0933606646492E-01 Mole fraction of component 3 3.3021452553679E-02 Mole fraction of component 4 3.2225742267063E-05 Mole fraction of component 5 6.0442404551918E+01 Molar mass 3.7326693612267E+00 Density 9.5243736092270E-06 Viscosity 2.1401634445368E-02 Thermal conductivity 9.5464535855951E+04 Heat capacity * Surface tension [Bottom product] 0 Stage Number 5.6246820808408E-02 Flow rate 3.6315000000000E+02 Temperature [K] 1.8645492414872E+05 Pressure [Pa] -2.6973283948953E+07 Enthalpy [J/kmol] -6.3630674127413E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.2140943440408E-02 Mole fraction of component 1 2.0322628512718E-03 Mole fraction of component 2 4.9965228493711E-01 Mole fraction of component 3 4.6340694338799E-01 Mole fraction of component 4 1.2767565383223E-02 Mole fraction of component 5 5.6246820808408E-02 Flow rate 2.2140943440408E-02 Mole fraction of component 1 2.0322628512718E-03 Mole fraction of component 2 4.9965228493711E-01 Mole fraction of component 3 4.6340694338799E-01 Mole fraction of component 4 1.2767565383223E-02 Mole fraction of component 5 9.7862154583010E+01 Molar mass 8.0004724629160E+02 Density 2.9526025813996E-04 Viscosity 1.1550758214271E-01 Thermal conductivity 1.9857050953038E+05 Heat capacity 1.9959416665075E-02 Surface tension [Flash Heat Duty] 5.626229967E+04 [K-values] Component K-values: 1 2.304371506E+01 2 2.332408109E+01 3 8.192418584E-01 4 7.125800126E-02 5 2.524031896E-03 [Estimated NRTL Data] i j Aij Aji `ij 1 2 2.22306E+02 6.21838E+01 2.00000E-01 1 3 2.04730E+03 -5.22191E+02 2.00000E-01 1 4 3.78240E+03 -2.91481E+03 2.00000E-01 1 5 -5.89059E+03 8.06339E+03 2.00000E-01 2 3 2.36743E+03 -1.19322E+03 2.00000E-01 2 4 3.30447E+03 -2.86169E+03 2.00000E-01 2 5 -6.53812E+03 9.33617E+03 2.00000E-01 3 4 8.01536E+03 -3.39114E+03 3.69300E-01 3 5 -3.47543E+03 4.06663E+03 2.00000E-01 4 5 -1.80794E+03 1.97027E+03 2.00000E-01 [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess 1 Converged 0 Iterations "ChemSep (TM) - COL2 6.90 Copyright (c) 1988-2012 Harry Kooijman and Ross Taylor License: 2100- 6 LITE free license Build: 6494e2b69d23 Checking data file C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_C_F~1.SEP Cape Open unit name: Flash Tank Cape-Open unit id: CS_C_F94_1CCE244_7261B040 Cape-Open run level: normal Cape open Initialized Cape Open Thermodynamic-properties disabled Reading configuration Reading component property libraries Warning! Fuller diffusion volume estimated (p-diisopropylbenzene) Ignoring all warnings User choice: Ignore Reading thermodynamic property options Reading physical property options Reading thermodynamic property data Warning! Estimating thermodynamic model parameters Ignoring all warnings User choice: Ignore Reading specifications Checking Component Data 74-98-6 Propane 115-07-1 Propylene 71-43-2 Benzene 98-82-8 Cumene 100-18-5 p-diisopropylbenzene * No class * Missing STboil * Missing Cp gas 1 * Missing V-Tc * Missing L-viscosity * Missing L-Cp * Missing L-Tc * Missing L-density Determining feed conditions Solving PV flash Reading flash specifications Reading old results Solving TV flash Iteration p Error 1 1.8644E+05 17.0060 2 1.8645E+05 -8.3517 Convergence obtained Time 16 milliseconds FixMem driver done run time: 0.16 seconds Using: C:\Program Files\ChemSepL6v90\bin\co-col2.exe CAPE-OPEN thermo-properties were disabled. All calculation methods have been determined by ChemSep. See output report or graphical user interface for more information. @G* not all ports are connectedFeed1{split-below}_stage1 TopProduct BottomProduct  @$@@@$@@ @$@@@$@@@$@@?@@@333333?@K$I$ @Ҷm۶mۿMakeUpMixer_197MakeUpMixer - mixer for determining a make-up flow rate/!TLCcxCOUSCOUS0002Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Outlet flowTarget flow at recycle outlet?L@ _BNet flowResulting net make up flow? _B Flow basisBasis for target and net flowmol/smol/smol/skg/sTarget compound&Compound for outlet flow specification Total flow Total flow Total flowPropane PropyleneBenzeneCumenep-diisopropylbenzeneLast run+++ specifications +++ Flow basis: mol/s Outlet flow: 57.5 mol/s +++ run results ++ Net flow: 27.8301409800603 mol/s   $not all material ports are connectedMake up excess flow Recycle inletMake up surplus flowRecycle outlet 0?@@?@@@ @ @FEHE;HeatExchanger - transfers heat from a hot to a cold stream.zT?H=M-~@ COUSCOUS0002 Type#Type of heat transfer specification Heat exchange Heat transfer Heat exchange Temperature Heat transferMax. heat transfer TemperatureTemperature of outlet stream 1?;r8@ _B Heat exchange/Heat transferred from hot stream to cold stream@?@`2A@xD Heat transfer8Heat transferred from hot stream to cold stream per area@?@jQp@@xDModeOperation modecounter-currentcounter-current co-currentcounter-currentPressure drop stream 1Pressure drop along stream 1?? _BPressure drop stream 2Pressure drop along stream 2?? _BAdapt outlet temperaturesEContinues calculation with limiting outlet temperatures if necessary.Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Tolerance4Relative termination tolerance on iterative solution-C6?-C6?|=?Maximum iterations/Maximum iterations to obtain iterative solutiondd Last runQ+++ specifications +++ Pressure drop stream 1: 0 Pa Pressure drop stream 2: 0 Pa Heat exchange: 1180000 W Adapt outlet temperatures: true Tolerance: 0.0001 Maximum iterations: 100 +++ solution +++ +++ optional parameters +++ Temperature: 579.998642202066 K Heat transfer: 9952.63290660576 W/K Mode: counter-current BL $not all material ports are connectedInlet1Inlet2Outlet1Outlet2   $@@@@@@@ @@ @@ @@ @@ @@@@@@@ @@ @@ @@@ @@@ @@@ @Pump_22>Pump - unit increasing the pressure due to the work performed.F^KsHSѪ2RhCOUSCOUS0002Pressure spec.$Pressure increase specification typePressurePressure increasePressure increasePressure Energy spec. Energy demand specification type Efficiency Efficiency Energy demand EfficiencyEnergy specification streamPressure increasePressure increase??AA _BPressureOutlet pressure?CAj@ _B Energy demandEnergy consumed by the pump@?@Bℶ@@xDAdiabatic efficiencyPump adiabatic efficiency???Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Pressure: 2500000 Pa Adiabatic efficiency: 0.75 +++ optional parameters +++ Pressure increase: 2325000 Pa Energy demand: 8553.7633825402 W Adiabatic efficiency: 0.75 ! $not all material ports are connected InletOutlet@@?K(^&?@@@@?:t= @@?:t= @@?:t= @@?:t= @@?:t= @@@MS Sans/C6?/C6?h㈵>/C6?"@)r)T@۶m۶mJ@aR@۶m۶mJ@aR@)r)T@۶m۶mJ@۶m۶mJ@ @ @@*r)r[@۶m۶mK@ayY@۶m۶mK@ayY@*r)r[@۶m۶mK@۶m۶mK@ @ @{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 110 kmol/h C\sub 3\super =\nosupersub 0.95 \par 25\super o\nosupersub C C\sub 3\nosupersub 0.05 \par } `g@H@@2@43333B@{۶m۶ @:: @{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 100.2 kmol/h \par 25\super o\nosupersub C \par } @[@H@p۶m6(@m۶m7@r۶m60@%I$I5@~{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 +3.4 MW \par } T@;@$I$L@zP@$I$I@$I$I @{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 210\super o\nosupersub C \par 25 bar\fs29 \par } N@H@I$ItP@ֶm۶-S@,I$I%@J$I$0@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 307\super o\nosupersub C\fs29 \par } L@;@R@@T@+I$I%@%I$I*@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 374\super o\nosupersub C \par } L@;@%I$IU@X|W|UW@s۶m۶$@ uPuP*@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 419\super o\nosupersub C\fs29 \par } L@;@$I$YS@W|WT@43333?{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 335\super o\nosupersub C\fs29 \par } L@;@M@33333CP@m۶mXW|W?{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 90\super o\nosupersub C \par } G@;@$I$iI@$I$IL@'I$I@@8B@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 -4.4 MW\fs29 \par } R@;@G@lK@$I$9@c_<@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 -1.46 MW\fs29 \par } @U@;@%I$IT@W@$I$ @@oA@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 -1.57 MW\fs29 \par } @U@;@[@hffff]@m۶m[?@DAA@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 +1.93 MW\fs29 \par } V@;@۶m۶=S@AAU@ܶm۶ R@R@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 +1.42 MW\fs29 \par } V@;@$I$[@]@۶m۶ R@R@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 106.8 kmol/h; 54\super o\nosupersub C; \par C\sub 3\super =\nosupersub 0.004; C\sub 3\nosupersub 0.04; B 0.946 \par } @l@H@P@$I$IV@߶m۶1@FA6@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 RR = 0.44 \par } @V@;@$I$YU@$I$W@&I$IE@8G@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 RR = 0.63 \par x\sub Cumene\nosupersub =0.999 \par } @^@H@n۶m[@;:^@E@533333H@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 x\sub Benzene\nosupersub =0.0005 \par } `@;@J$ItV@++Y@o۶mR@R@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 1.75 bar \par } R@;@o۶mR@o۶mFT@ݶm۶-B@DAC@~{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 1 bar \par } I@;@$I$Y@$I$Y[@A@hffff&C@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 1.18 MW\fs29 \par } S@;@I$IP@R@$I$I++ z{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 2 \par } 1@;@$I$S@@T@@D@hffffE@z{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 8 \par } 1@;@$I$S@W|WLT@@I@hffffJ@{{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 14 \par } ;@;@S@43333T@ݶm۶-O@JP@z{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 2 \par } 1@;@$I$YZ@Z@&I$IC@8E@{{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 12 \par } ;@;@PZ@53333[@m۶mJ@AԁK@{{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 19 \par } ;@;@PZ@53333[@N@43333P@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 2.54 kmol/h\fs29 \par } X@;@$I$Y]@$I$_@ܶm۶P@@Q@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 93.1 kmol/h\fs29 \par } X@;@%I$I"]@%I$I_@o۶mB@AA]D@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\f0\fs27 10.2 kmol/h; 90\super o\nosupersub C; \par C\sub 3\super =\nosupersub 0.047; C\sub 3\nosupersub 0.51; B 0.403 \par } @l@H@I$IW@۶m۶]@)I$I5@9@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 X\sub Cumene\nosupersub = 0.965 \par X\sub pDIB \nosupersub = 0.026\b0\fs29 \par } `@H@ܶm۶W@@[@$I$I?++@ׁ?ׁ?ׁ?ׁ??Z